1 atm Catalytic Hydrogenation NaBH4-Ni Acetate

[Rhodium]

https://www.thevespiary.org/rhodium/Rhodium/pdf/borohydride.p2.nickel.pdf

Nickel(II)Acetate tetrahydrate and sodium borohydride easily reduces a variety of alkenes alkynes and dienes selectively.

Perhaps it can reduce nitroalkenes too?

[Osmium]

Haven't looked at it (too tired, lazy and confused right now) but me thinks to reduce nitroalkenes you generally need a strong, fast and nonselective catalyst+reducing agent system under more drastic condidions, not a selective one.
I'm not fat just horizontally disproportionate.

[Barium]

I´ve made and tried both P1- and P2-NiB/NaBH4 and got quite good results from reducing both ketoximes and nitroalkanes, but crap when tried with nitroalkenes.
Catalytic hydrogenation freak

[Rhodium]

Can you fuel the above hydrogenation by in situ generation of hydrogen from NaBH4, or do you have to generate it externally?

[Barium]

Both the P1- and P2-NiB were generated externally and the H2(g) internally.
Catalytic hydrogenation freak